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1

Recovery of host crystals from inclusion crystals of p-tert-butylcalix[4]arene and p-tert-butylthiacalix[4]arene by the treatment with a solvent and/or supercritical CO2

Morohashi, Naoya, Ebata, Kohei, Hattori, Tetsutaro

Journal:

Journal of Inclusion Phenomena and Macrocyclic Chemistry

Année:

2018

Langue:

english

Fichier:

PDF, 1.01 MB

english, 2018

2

Selective guest inclusion by crystals of calixarenes: potential for application as separation materials

Morohashi, Naoya, Hattori, Tetsutaro

Journal:

Journal of Inclusion Phenomena and Macrocyclic Chemistry

Année:

2018

Langue:

english

Fichier:

PDF, 3.39 MB

english, 2018

3

Zinc(II) Slides on a Ligand Surface: The X-Ray Crystal Structure and Dynamic Behavior in Solution of [Zn(H2L)(tacn)]

Takashi Kajiwara, Shuichi Yokozawa, Tasuku Ito, Nobuhiko Iki, Naoya Morohashi, Sotaro Miyano

Journal:

Angewandte Chemie

Année:

2002

Langue:

english

Fichier:

PDF, 101 KB

english, 2002

4

Zinc(II) Slides on a Ligand Surface: The X-Ray Crystal Structure and Dynamic Behavior in Solution of [Zn(H2L)(tacn)]

Takashi Kajiwara, Shuichi Yokozawa, Tasuku Ito, Nobuhiko Iki, Naoya Morohashi, Sotaro Miyano

Journal:

Angewandte Chemie International Edition

Année:

2002

Langue:

english

Fichier:

PDF, 101 KB

english, 2002

5

ChemInform Abstract: Novel Molecular Receptors Based on a Thiacalix[4]arene Platform. Preparations of the Di- and Tetracarboxylic Acid Derivatives and Their Binding Properties Towards Transition Metal Ions.

Nobuhiko Iki, Naoya Morohashi, Fumitaka Narumi, Toyohisa Fujimoto, Tomohiro Suzuki, Sotaro Miyano

Journal:

Année:

1999

Fichier:

PDF, 26 KB

1999

6

ChemInform Abstract: Highly Stereospecific Conversion of C-Centrochirality of a 3,4-Dihydro-2H-1,1′-binaphthalen-1-ol into Axial Chirality of a 3,4-Dihydro-1,1′-binaphthalene.

Tetsutaro Hattori, Masamitsu Date, Kenta Sakurai, Naoya Morohashi, Hiroshi Kosugi, Sotaro Miyano

Journal:

Année:

2002

Fichier:

PDF, 29 KB

2002

7

ChemInform Abstract: Complexing Ability of p-tert-Butylthiacalix[6]arene Toward Metal Ions. Predominant Effect of Coordination by the Bridging Sulfur Rather than that of the Ring-Size.

Naoya Morohashi, Nobuhiko Iki, Mitsuru Aono, Satoro Miyano

Journal:

Année:

2002

Fichier:

PDF, 28 KB

2002

8

Thiacalixarene. A New Molecular Scaffold for Host Molecules

Naoya Morohashi, Nobuhiko Iki, Sotaro Miyano

Journal:

Année:

2002

Fichier:

PDF, 25 KB

2002

9

First Synthesis of 25,26-Bridged Thiacalix[4]crowns by the Use of a 25,26-O-Disiloxanediyl-Capped p-tert-Butylthiacalix[4]arene.

Fumitaka Narumi, Nobuji Matsumura, Naoya Morohashi, Hiroshi Kameyama, Sotaro Miyano

Journal:

Année:

2002

Fichier:

PDF, 26 KB

2002

10

Dinuclear Titanium(IV) Complex of p-tert-Butylthiacalix[4]arene as a Novel Bidentate Lewis Acid Catalyst.

Naoya Morohashi, Tetsutaro Hattori, Katsuya Yokomakura, Chizuko Kabuto, Sotaro Miyano

Journal:

Année:

2003

Fichier:

PDF, 106 KB

2003

11

Synthesis, Resolution, and Absolute Stereochemistry of (-)-Blestriarene C.

Tetsutaro Hattori, Yuhi Shimazumi, Hitoshi Goto, Osamu Yamabe, Naoya Morohashi, Wataru Kawai, Sotaro Miyano

Journal:

Année:

2003

Fichier:

PDF, 59 KB

2003

12

ChemInform Abstract: Carboxylation of Indoles and Pyrroles with CO2 in the Presence of Dialkylaluminum Halides.

Koji Nemoto, Satoru Onozawa, Naoki Egusa, Naoya Morohashi, Tetsutaro Hattori

Journal:

Année:

2009

Fichier:

PDF, 27 KB

2009

13

ChemInform Abstract: Direct Carboxylation of Arenes and Halobenzenes with CO2 by the Combined Use of AlBr3 and R3SiCl.

Koji Nemoto, Hiroki Yoshida, Naoki Egusa, Naoya Morohashi, Tetsutaro Hattori

Journal:

Année:

2011

Fichier:

PDF, 39 KB

2011

14

Synthesis of hybrid calix[6]arenes having both methylene and epithio bridging groups

Naoya Morohashi, Tomohiro Ishiwata, Kazuaki Ito, Yoshihiro Ohba

Journal:

Tetrahedron Letters

Année:

2004

Langue:

english

Fichier:

PDF, 267 KB

english, 2004

15

Highly regioselective [2+2+2] cycloaddition of terminal alkynes catalyzed by titanium complexes of p-tert-butylthiacalix[4]arene

Naoya Morohashi, Katsuya Yokomakura, Tetsutaro Hattori, Sotaro Miyano

Journal:

Tetrahedron Letters

Année:

2006

Langue:

english

Fichier:

PDF, 130 KB

english, 2006

16

Synthesis and X-ray structures of iodothiacalix[4]arenes

Shinya Tanaka, Hiroshi Katagiri, Naoya Morohashi, Tetsutaro Hattori, Sotaro Miyano

Journal:

Tetrahedron Letters

Année:

2007

Langue:

english

Fichier:

PDF, 236 KB

english, 2007

17

Intramolecular rearrangement of 1,3-bistriflate ester of thiacalix[4]arene to 1,2-counterpart: an efficient di-O-protection method for the stereoselective synthesis of anti-1,2-diethers

Ryuichi Serizawa, Shinya Tanaka, Naoya Morohashi, Fumitaka Narumi, Tetsutaro Hattori

Journal:

Tetrahedron Letters

Année:

2007

Langue:

english

Fichier:

PDF, 149 KB

english, 2007

18

Ullmann coupling reaction of 1,3-bistriflate esters of calix[4]arenes: facile syntheses of monoaminocalix[4]arenes and 4,4′:6,6′-diepithiobis(phenoxathiine)

Shinya Tanaka, Ryuichi Serizawa, Naoya Morohashi, Tetsutaro Hattori

Journal:

Tetrahedron Letters

Année:

2007

Langue:

english

Fichier:

PDF, 181 KB

english, 2007

19

Crystallization-based optical resolution of 1,1′-binaphthalene-2,2′-dicarboxylic acid via 1-phenylethylamides: control by the molecular structure and dielectric property of solvent

Yuki Kato, Yuichi Kitamoto, Naoya Morohashi, Yosuke Kuruma, Shuichi Oi, Kenichi Sakai, Tetsutaro Hattori

Journal:

Tetrahedron Letters

Année:

2009

Langue:

english

Fichier:

PDF, 1.20 MB

english, 2009

20

Crystal structure and inclusion property of p-tert-butylthiacalix[6]arene

Nobuhiko Iki, Naoya Morohashi, Tomohiro Suzuki, Satoshi Ogawa, Mitsuru Aono, Chizuko Kabuto *, Hitoshi Kumagai *, Haruhiko Takeya, Setsuko Miyanari, Sotaro Miyano *

Journal:

Tetrahedron Letters

Année:

2000

Langue:

english

Fichier:

PDF, 145 KB

english, 2000

21

Novel molecular chirality in the calixarene family: formation of chiral disulfinyldithiacalix[4]arenes via partial oxidation of two adjacent sulfides of tetrathiacalix[4]arene

Naoya Morohashi, Nobuhiko Iki, Toru Onodera, Chizuko Kabuto, Sotaro Miyano *

Journal:

Tetrahedron Letters

Année:

2000

Langue:

english

Fichier:

PDF, 161 KB

english, 2000

22

Highly stereospecific conversion of C-centrochirality of a 3,4-dihydro-2H-1,1′-binaphthalen-1-ol into axial chirality of a 3,4-dihydro-1,1′-binaphthalene

Tetsutaro Hattori, Masamitsu Date, Kenta Sakurai, Naoya Morohashi, Hiroshi Kosugi, Sotaro Miyano

Journal:

Tetrahedron Letters

Année:

2001

Langue:

english

Fichier:

PDF, 90 KB

english, 2001

23

Proximal O,O′-capped calix[4]arenes with a disiloxane bridge as highly efficient synthetic intermediates for 1,2-dialkylation at the lower rim

Fumitaka Narumi, Naoya Morohashi, Nobuji Matsumura, Nobuhiko Iki, Hiroshi Kameyama, Sotaro Miyano

Journal:

Tetrahedron Letters

Année:

2002

Langue:

english

Fichier:

PDF, 88 KB

english, 2002

24

Dinuclear titanium(IV) complex of p-tert-butylthiacalix[4]arene as a novel bidentate Lewis acid catalyst

Naoya Morohashi, Tetsutaro Hattori, Katsuya Yokomakura, Chizuko Kabuto, Sotaro Miyano

Journal:

Tetrahedron Letters

Année:

2002

Langue:

english

Fichier:

PDF, 146 KB

english, 2002

25

Selective oxidation of thiacalix[4]arenes to the sulfinyl- and sulfonylcalix[4]arenes and their coordination ability to metal ions

Nobuhiko Iki, Hitoshi Kumagai, Naoya Morohashi, Kohki Ejima, Mitsuharu Hasegawa, Setsuko Miyanari, Sotaro Miyano

Journal:

Tetrahedron Letters

Année:

1998

Langue:

english

Fichier:

PDF, 248 KB

english, 1998

26

Novel molecular receptors based on a thiacalix[4]arene platform. Preparations of the di- and tetracarboxylic acid derivatives and their binding properties towards transition metal ions

Nobuhiko Iki, Naoya Morohashi, Fumitaka Narumi, Toyohisa Fujimoto, Tomohiro Suzuki, Sotaro Miyano

Journal:

Tetrahedron Letters

Année:

1999

Langue:

english

Fichier:

PDF, 300 KB

english, 1999

27

Carboxylation of indoles and pyrroles with CO2 in the presence of dialkylaluminum halides

Koji Nemoto, Satoru Onozawa, Naoki Egusa, Naoya Morohashi, Tetsutaro Hattori

Journal:

Tetrahedron Letters

Année:

2009

Langue:

english

Fichier:

PDF, 170 KB

english, 2009

28

Selective oxidation of thiacalix[4]arenes to the sulfinyl and sulfonyl counterparts and their complexation abilities toward metal ions as studied by solvent extraction

Naoya Morohashi, Nobuhiko Iki, Atsushi Sugawara, Sotaro Miyano

Journal:

Année:

2001

Langue:

english

Fichier:

PDF, 171 KB

english, 2001

29

Stereocontrolled oxidation of a thiacalix[4]arene to the sulfinyl counterpart of a defined SO configuration

Naoya Morohashi, Nobuhiko Iki, Chizuko Kabuto, Sotaro Miyano *

Journal:

Tetrahedron Letters

Année:

2000

Langue:

english

Fichier:

PDF, 168 KB

english, 2000

30

Crystal Structures of Mono-, Di-, and Tri(p-tert-butyl)-thiacalix[4]arenes: Dimeric Self-inclusion Behavior

Chizuko Kabuto, Yutaka Higuchi, Tomohiro Niimi, Fumio Hamada, Nobuhiko Iki, Naoya Morohashi, Sotaro Miyano

Journal:

Journal of Inclusion Phenomena and Macrocyclic Chemistry

Année:

2002

Langue:

english

Fichier:

PDF, 232 KB

english, 2002

31

ChemInform Abstract: Direct Carboxylation of Thiophenes and Benzothiophenes with the Aid of EtAlCl2.

Koji Nemoto, Satoru Onozawa, Megumi Konno, Naoya Morohashi, Tetsutaro Hattori

Journal:

Année:

2012

Fichier:

PDF, 34 KB

2012

32

Selective synthesis of three conformational isomers of tetrakis[(ethoxycarbonyl)methoxy]thiacalix[4]arene and their complexation properties towards alkali metal ions †

Iki, Nobuhiko, Narumi, Fumitaka, Fujimoto, Toyohisa, Morohashi, Naoya, Miyano, Sotaro

Journal:

Journal of the Chemical Society Perkin Transactions 2

Année:

1998

Langue:

english

Fichier:

PDF, 236 KB

english, 1998

33

Syntheses of inherently chiral monosulfinyltrithiacalix[4]arenes by the oxidation of one of the bridging sulfurs of a tetrathiacalix[4]arene fixed in the 1,3-alternate conformation

Naoya Morohashi, Ryoichiro Naito, Nobuhiko Iki, Sotaro Miyano

Journal:

Israel Journal of Chemistry

Année:

2001

Langue:

english

Fichier:

PDF, 133 KB

english, 2001

34

Energy transfer luminescence of Tb3+ ion complexed with calix[4]arenetetrasulfonate and the thia and sulfonyl analogue. The effect of bridging groupsElectronic supplementary information (ESI) available: emission spectra of Sm3+ and Dy3+ ions complexed with 2; emission spectra of Sm3+, Eu3+ and Dy3+ complexed with 3; continuous variation curves for the Tb3+ complexes with 2 and 3. See http://www.rsc.org/suppdata/p2/b0/b009151k/

Iki, Nobuhiko, Horiuchi, Takayuki, Oka, Hiromi, Koyama, Katsuyoshi, Morohashi, Naoya, Kabuto, Chizuko, Miyano, Sotaro

Journal:

Journal of the Chemical Society Perkin Transactions 2

Année:

2001

Langue:

english

Fichier:

PDF, 335 KB

english, 2001

35

Thiacalixarenes

Morohashi, Naoya, Narumi, Fumitaka, Iki, Nobuhiko, Hattori, Tetsutaro, Miyano, Sotaro

Journal:

Chemical Reviews

Année:

2006

Langue:

english

Fichier:

PDF, 1.75 MB

english, 2006

36

Direct Carboxylation of Arenes and Halobenzenes with CO 2 by the Combined Use of AlBr 3 and R 3 SiCl

Nemoto, Koji, Yoshida, Hiroki, Egusa, Naoki, Morohashi, Naoya, Hattori, Tetsutaro

Journal:

Journal of Organic Chemistry

Année:

2010

Langue:

english

Fichier:

PDF, 939 KB

english, 2010

37

Conformational Behaviors of Tetra- O- methylsulfinylcalix[4]arenesAn Approach to Control the Conformation of Thiacalix[4]arenes by Oxidizing Sulfur Bridges

Katagiri, Hiroshi, Hattori, Tetsutaro, Morohashi, Naoya, Iki, Nobukiho, Miyano, Sotaro

Journal:

Journal of Organic Chemistry

Année:

2007

Langue:

english

Fichier:

PDF, 149 KB

english, 2007

38

Synthesis of All Stereoisomers of Sulfinylcalix[4]arenes 1

Morohashi, Naoya, Katagiri, Hiroshi, Iki, Nobuhiko, Yamane, Yusuke, Kabuto, Chizuko, Hattori, Tetsutaro, Miyano, Sotaro

Journal:

Journal of Organic Chemistry

Année:

2003

Langue:

english

Fichier:

PDF, 225 KB

english, 2003

39

Sulfonyl-bridged oligo(benzoic acid)s: synthesis, X-ray structures, and properties as metal extractants

Naoya Morohashi, Kazutoshi Nagata…

Journal:

Journal of Inclusion Phenomena and Macrocyclic Chemistry

Année:

2014

Langue:

english

Fichier:

PDF, 629 KB

english, 2014

40

Unique Inclusion Properties of Crystalline Powder p - tert -Butylthiacalix[4]arene toward Alcohols and Carboxylic Acids

Morohashi, Naoya, Noji, Shintaro, Nakayama, Hiroko, Kudo, Yasutaka, Tanaka, Shinya, Kabuto, Chizuko, Hattori, Tetsutaro

Journal:

Organic Letters

Année:

2011

Langue:

english

Fichier:

PDF, 1.05 MB

english, 2011

41

Synthesis of Mono- and 1,3-Diaminocalix[4]arenes via Ullmann-Type Amination and Amidation of 1,3-Bistriflate Esters of Calix[4]arenes

Nakamura, Yuka, Tanaka, Shinya, Serizawa, Ryuichi, Morohashi, Naoya, Hattori, Tetsutaro

Journal:

Journal of Organic Chemistry

Année:

2011

Langue:

english

Fichier:

PDF, 1.29 MB

english, 2011

42

Switching of the Diastereomer Deposited during the Crystallization of N -[( S )-1-Phenylethyl]-2′-carbamoyl-1,1′-binaphthalene-2-carboxylic Acid: Investigation of the Mechanism of Dielectrically Controlled Resolution

Kitamoto, Yuichi, Suzuki, Kazumi, Morohashi, Naoya, Sakai, Kenichi, Hattori, Tetsutaro

Journal:

Journal of Organic Chemistry

Année:

2013

Langue:

english

Fichier:

PDF, 2.86 MB

english, 2013

43

Synthesis, Resolution, and Absolute Stereochemistry of (−)-Blestriarene C

Hattori, Tetsutaro, Shimazumi, Yuhi, Goto, Hitoshi, Yamabe, Osamu, Morohashi, Naoya, Kawai, Wataru, Miyano, Sotaro

Journal:

Journal of Organic Chemistry

Année:

2003

Langue:

english

Fichier:

PDF, 239 KB

english, 2003

44

Synthesis of Dinuclear Boron Complexes of Sulfinylcalix[4]arenes: Syn/Anti Stereocontrol by the Arrangement of the Sulfinyl Functions

Morohashi, Naoya, Kitahara, Tsuyoshi, Arima, Tomoko, Tanaka, Shinya, Ohba, Yoshihiro, Hattori, Tetsutaro

Journal:

Organic Letters

Année:

2008

Langue:

english

Fichier:

PDF, 458 KB

english, 2008

45

Synthesis of novel dihydroxydiphosphines and dihydroxydicarboxylic acids having a tetra(thio-1,3-phenylene-2-yl) backbone

Akahira, Yuki, Nagata, Kazutoshi, Morohashi, Naoya, Hattori, Tetsutaro

Journal:

Supramolecular Chemistry

Année:

2011

Langue:

english

Fichier:

PDF, 577 KB

english, 2011

46

Pd(ii) Complexes with thiacalix[4]-arene and -aniline; subtle, but distinct influences of phenol and aniline units on the 3-D structureThe X-ray structure for thiacalix[4]aniline-Pd(ii) was first reported in a communication.8

Katagiri, Hiroshi, Morohashi, Naoya, Iki, Nobuhiko, Kabuto, Chizuko, Miyano, Sotaro

Journal:

Dalton Transactions

Année:

2003

Langue:

english

Fichier:

PDF, 194 KB

english, 2003

47

Stereoselective dialkylation of the proximal hydroxy groups of calix- and thiacalix[4]arenes

Narumi, Fumitaka, Hattori, Tetsutaro, Morohashi, Naoya, Matsumura, Nobuji, Yamabuki, Waka, Kameyama, Hiroshi, Miyano, Sotaro

Journal:

Organic & Biomolecular Chemistry

Année:

2004

Langue:

english

Fichier:

PDF, 291 KB

english, 2004

48

First synthesis of 25,26-bridged thiacalix[4]crowns by the use of a 25,26-O-disiloxanediyl-capped p-tert-butylthiacalix[4]arene

Narumi, Fumitaka, Matsumura, Nobuji, Morohashi, Naoya, Kameyama, Hiroshi, Miyano, Sotaro

Journal:

Journal of the Chemical Society Perkin Transactions 1

Année:

2002

Langue:

english

Fichier:

PDF, 82 KB

english, 2002

49

Regioselective synthesis of 1,2- and 1,3-diaminothiacalix[4]arenes via nucleophilic aromatic substitution and their X-ray structures

Katagiri, Hiroshi, Tanaka, Shinya, Ohkubo, Kazuya, Akahira, Yuki, Morohashi, Naoya, Iki, Nobukiho, Hattori, Tetsutaro, Miyano, Sotaro

Journal:

Année:

2014

Langue:

english

Fichier:

PDF, 976 KB

english, 2014

50

1,3-Diiodocalix[4]arene: Synthesis by Ullmann-Type Iodination of 1,3-Bistriflate Ester of Calix[4]arene, Conformational Analysis, and Transformation into 1,3-Dicarboxy-, Diformyl-, and Dialkylcalix[4]arenes

Tanaka, Shinya, Umetsu, Takafumi, Nebuya, Satoru, Morohashi, Naoya, Hattori, Tetsutaro

Journal:

Journal of Organic Chemistry

Année:

2015

Langue:

english

Fichier:

PDF, 9.22 MB

english, 2015